Synthesis and characterization of macromonomer crosslinker: Towards the study of the effect of crosslinking on latex film formation.

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International Rubber Conference 1997

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File	Description	Size	Format
ARTICLE	Article	607 KB	Adobe Acrobat PDF
METADATA	Article Metadata	3 KB	XML Document
SOURCE1	DocumentNavigator Document	2 KB	XML Document
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Title: Synthesis and characterization of macromonomer crosslinker: Towards the study of the effect of crosslinking on latex film formation.
Creator: Hafsah bt. Mohd. Ghazaly
Creator: Daniels, E.S.
Creator: Dimonie, V.L.
Creator: El-Aasser, M.S.
Creator: Klein, A.
Contributor: SAUID|SAUID
Subject: Conference
Subject: PRRIM
Date: 20030923 | 20030923 | | 1997 | | | | | | |
Description: A macromonomer crosslinker with a number average molecular weight,Mn -3300 ± 100 g/mol (obtained from gel permeation chromatography)was synthesized from a hydroxy-terminated,saturated ethylene-butylene polymer by reaction with acrylic acid.Preservation of the double bonds was achieved by inhibiting the reaction utilizing methyl hydroquinone with nitrobenzene and oxygen or t-butylcatechol and oxygen.Purification of the reacted mixture with aqueous sodium hydroxide or solid sodium bicarbonate gave similar products.Characterization of the macromonomer crosslinker and comparison with the diol precurser were made using dilute solution viscosity,gel permeation chromatograpy,Fourier transform infrared spectroscopy and ‘HNMR spectroscopy.The crosslinking ability was verified by the formation of an insoluble gel of the macromonomer in solution homopolymerizations and also in solution copolymerizations with a primary monomer,n-butyl methacrylate in the presence of 2,2’-azobis(isobutyronitrile)(AIBN)at 70 °C.

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collection(s): International Rubber Conference 1997
Identifier: vital1:25669
Format: application/pdf
Coverage: International Rubber Conference 1997
Relation: 6AA-1,29,39
Relation: In: Int. Rubb. Conf. 1997, 6-9 October 1997, Kuala Lumpur, p.29-39
Rights: Yes|No
Type: Article
Source: External/Others

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Hafsah bt. Mohd. Ghazaly, Daniels, E.S., Dimonie, V.L., El-Aasser, M.S., Klein, A.. Synthesis and characterization of macromonomer crosslinker: Towards the study of the effect of crosslinking on latex film formation.. 20030923 | 20030923 | | 1997 | | | | | | |.

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International Rubber Conference 1997

Synthesis and characterization of macromonomer crosslinker: Towards the study of the effect of crosslinking on latex film formation.

VITAL Repository 5.2